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Question

Question: Which of the following is the most stable free redical?...

Which of the following is the most stable free redical?

A

CH3CH2CH_{3}\overset{\bullet}{C}H_{2}

B

CH3CHCH3CH_{3}\overset{\bullet}{C}HCH_{3}

C

CH3CHC6H5CH_{3}\overset{\bullet}{C}HC_{6}H_{5}

D

C6H5CH2CH2C_{6}H_{5}CH_{2}\overset{\bullet}{C}H_{2}

Answer

CH3CHC6H5CH_{3}\overset{\bullet}{C}HC_{6}H_{5}

Explanation

Solution

: The stability order of free radicals are 3>2>13^{{^\circ}} > 2^{{^\circ}} > 1^{{^\circ}}Because of hyperconjugation and resonance CH3CH6H5CH_{3}CH_{6}H_{5}is most stable.

shows both resonance and

Hyperconjugation