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Question

Chemistry Question on trends in periodic table

Which of the following is the most basic oxide?

A

Sb2O3Sb _{2} O _{3}

B

Bi2O3Bi_2O_3

C

SeO2SeO_2

D

Al2O3Al_2O_3

Answer

Bi2O3Bi_2O_3

Explanation

Solution

Bi2O3Bi _{2} O _{3} is the most basic oxide.
More the oxidation state of the central metal atom, more is its acidity. Hence , SeO2SeO _{2} (O.SO.S of Se=+4Se =+4) is acidic. Further, for a given oxidation state, the basic character of the oxides increases with increasing size of the central atom. Thus, Al2O3Al _{2} O _{3} and Sb2O3Sb _{2} O _{3} are amphoteric and Bi2O3Bi _{2} O _{3} is basic.