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Question

Chemistry Question on States of matter

Which of the following is the correct option for free expansion of an ideal gas under adiabatic condition?

A

q=0,ΔT0,W=0q=0, \Delta T\ne0, W=0

B

q=0,ΔT0,W0q=0, \Delta T\ne0, W\ne0

C

q=0,ΔT=0,W=0q=0, \Delta T=0, W=0

D

q=0,ΔT=0,W0q=0, \Delta T=0, W\ne0

Answer

q=0,ΔT=0,W=0q=0, \Delta T=0, W=0

Explanation

Solution

For the free expansion of an ideal gas, the opposing force is zero, hence work done = 0.
ΔU=q+w,w=0,henceΔU=q\Delta U=q+w, w=0, hence \Delta U=q
But the process is adiabatic, hence q = 0
q=0,ΔT=0,W=0\therefore q=0, \Delta T=0, W=0