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Question

Chemistry Question on Classification of elements & periodicity in properties

Which of the following is the correct electronic configuration of CrCr?

A

1s22s22p63s23p64s13d51 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{1} 3 d^{5}

B

1s22s22p63s23p64s23d41 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{2} 3 d^{4}

C

1s22s22p63s23p64s23d61 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{2} 3 d^{6}

D

1s22s22p63s23p64s13d81 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{1} 3 d^{8}

Answer

1s22s22p63s23p64s13d51 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{1} 3 d^{5}

Explanation

Solution

As we know that atomic number of chromium is 24 hence electronic configuration will be : 1s22s22p63s23p64s23d41 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{2} 3 d^{4} But in excited state one electron from 4s4 s-orbitals jumps to 3d3 d orbits and thus acquire stable configuration. Hence, the correct electronic configuration of CrCr will be : 1s22s22p63s23p64s13d51 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{1} 3 d^{5}