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Question

Chemistry Question on Chemical Reactions

Which of the following is obtained in a carbylamine reaction?

A

C6H5NH2{{C}_{6}}{{H}_{5}}N{{H}_{2}}

B

COCl2COC{{l}_{2}}

C

C6H5CN{{C}_{6}}{{H}_{5}}CN

D

C6H5NC{{C}_{6}}{{H}_{5}}NC

Answer

C6H5NC{{C}_{6}}{{H}_{5}}NC

Explanation

Solution

Carbylamine reaction involves the reaction of a primary amine with chloroform in presence of alkali. In this reaction, an offensive odorous compound, isocyanide, is obtained, e., C6H5NH2+CHCl3+3KOH{{C}_{6}}{{H}_{5}}N{{H}_{2}}+CHC{{l}_{3}}+3KOH\xrightarrow[{}]{{}} C6H5NC+3KCl+3H2O{{C}_{6}}{{H}_{5}}NC+3KCl+3{{H}_{2}}O