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Question

Chemistry Question on Surface Chemistry

Which of the following is not the characteristic of physisorption?

A

It arises because of vander Waals forces.

B

It is not specific in nature.

C

Enthalpy of adsorption is high.

D

It results into multi molecular layers on adsorbent surface under high pressure.

Answer

Enthalpy of adsorption is high.

Explanation

Solution

The characteristic of physisorption that is not correct is:

Enthalpy of adsorption is high.

Physisorption is characterized by weak van der Waals forces between the adsorbent and the adsorbate. As a result, the enthalpy of adsorption in physisorption is relatively low. The other options are correct:

  • Physisorption arises because of van der Waals forces.
  • Physisorption is not specific in nature.
  • Physisorption can result in the formation of multi-molecular layers on the adsorbent surface under high pressure.