Question
Chemistry Question on GROUP 1 ELEMENTS
Which of the following is not a similarity of beryllium with aluminium ?
It becomes passive when treated with conc. HNO3
It forms polymeric covalent hydrides
Carbonate of Be is extremely stable
Salts of Be do not impart colour to the flame
Carbonate of Be is extremely stable
Solution
Beryllium shows resemblance with its diagonally opposite element aluminium. Points of similarity are- Both metals have a tendency to form covalent bonds. Eg; Chlorides of both are being covalent are being soluble in organic solvents. Both BeCl2 and AlCl3 act as Lewis acids and are used as Friedal Kraft's catalyst. These two elements have the same electronegativity and polarizing power i.e. charge per radius ration of their ions are very similar. They form polymeric covalent hydrides. They become passive when treated with conc. HNO3 Salts of Be do not impart colour to the flame. But, the stability of Carbonate of Be is not similar to carbonate of Al.