Question
Chemistry Question on Nitrogen
Which of the following is most basic?
A
Benzamide
B
Butamine
C
Nitrobenzene
D
Benzene
Answer
Butamine
Explanation
Solution
- undefined
Does not show basic character because lone pair on nitrogen is delocalized by resonance with the carbonyl group which makes it less available for protonation -\underset{\text{(aliphatic primary amine)}}{{CH_{3}CH_{2}CH_{2}CH_{2} \overset{??{N}H_{2}}} R→NH2 R-group due to +1 effect intensify the electron density on nitrogen. Therefore highly basic in nature. -
−NO2 group (-I) effect, therefore makes the ring electron deficient. Hence, acidic in nature
(neutral)