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Question

Chemistry Question on Nitrogen

Which of the following is most basic?

A

Benzamide

B

Butamine

C

Nitrobenzene

D

Benzene

Answer

Butamine

Explanation

Solution

- undefined Does not show basic character because lone pair on nitrogen is delocalized by resonance with the carbonyl group which makes it less available for protonation -\underset{\text{(aliphatic primary amine)}}{{CH_{3}CH_{2}CH_{2}CH_{2} \overset{??{N}H_{2}}} RNH2R \to NH_{2} R-group due to +1+1 effect intensify the electron density on nitrogen. Therefore highly basic in nature. - NO2-NO_{2} group (-I) effect, therefore makes the ring electron deficient. Hence, acidic in nature (neutral)