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Question: Which of the following is a decreasing order of oxidation states of the central atoms?...

Which of the following is a decreasing order of oxidation states of the central atoms?

A

PCl5,HIO4,Cl2O72,Cl2OPCl_{5,}HIO_{4,}Cl_{2}O_{7}^{2 -},Cl_{2}O

B

Cr2O72,Cl2O,HIO4,PCl5Cr_{2}O_{7}^{2 -},Cl_{2}O,HIO_{4},PCl_{5}

C

HIO4,Cr2O72,PCl5,Cl2OHIO_{4},Cr_{2}O_{7}^{2 -},PCl_{5},Cl_{2}O

D

Cr2O72,HIO4,Cl2O,PCl5Cr_{2}O_{7}^{2 -},HIO_{4},Cl_{2}O,PCl_{5}

Answer

HIO4,Cr2O72,PCl5,Cl2OHIO_{4},Cr_{2}O_{7}^{2 -},PCl_{5},Cl_{2}O

Explanation

Solution

: Cl2O2x+1(2)=0x=+1Cl_{2}O \rightarrow 2x + 1( - 2) = 0 \Rightarrow x = + 1

Cr2O722x+7(2)=2x=+6Cr_{2}O_{7}^{2 -} \rightarrow 2x + 7( - 2) = - 2 \Rightarrow x = + 6

HIO4+1+x+4(2)=0x=+7HIO_{4} \rightarrow + 1 + x + 4( - 2) = 0 \Rightarrow x = + 7

PCl5x+(5)=0x=+5PCl_{5} \rightarrow x + ( - 5) = 0 \Rightarrow x = + 5