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Question

Question: Which of the following hydrides is least stable to hydrolysis?...

Which of the following hydrides is least stable to hydrolysis?

A

CH4\mathrm { CH } _ { 4 }

B

SiH4\mathrm { SiH } _ { 4 }

C

SnH4\mathrm { SnH } _ { 4 }

D

PbH4\mathrm { PbH } _ { 4 }

Answer

SiH4\mathrm { SiH } _ { 4 }

Explanation

Solution

: Silicon hydrides are most easily hydrolysed.

SiH4+3H2OH2SiO3+4H2\mathrm { SiH } _ { 4 } + 3 \mathrm { H } _ { 2 } \mathrm { O } \rightarrow \mathrm { H } _ { 2 } \mathrm { SiO } _ { 3 } + 4 \mathrm { H } _ { 2 }

SiH4+2NaOH+H2ONa2SiO3+4H2\mathrm { SiH } _ { 4 } + 2 \mathrm { NaOH } + \mathrm { H } _ { 2 } \mathrm { O } \rightarrow \mathrm { Na } _ { 2 } \mathrm { SiO } _ { 3 } + 4 \mathrm { H } _ { 2 }