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Question

Question: Which of the following has no unpaired electrons but is coloured?...

Which of the following has no unpaired electrons but is coloured?

A

K2Cr2O7K_{2}Cr_{2}O_{7}

B

K2MnO4K_{2}MnO_{4}

C

CuSO4.5H2OCuSO_{4}.5H_{2}O

D

MnCl2MnCl_{2}

Answer

K2Cr2O7K_{2}Cr_{2}O_{7}

Explanation

Solution

In K2Cr2O7,K_{2}Cr_{2}O_{7}, the oxidation number of Cr = +6

The electronic configuration of Cr6+Cr^{6 +}is

24C6+[Ar]3d04s024C^{6 +} \rightarrow \lbrack Ar\rbrack 3d^{0}4s^{0}

So it has no unpaired electron but is orange coloured.