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Question

Chemistry Question on Classification of elements & periodicity in properties

Which of the following has highest ionization enthalpy?

A

PP

B

NN

C

AsAs

D

SbSb

Answer

NN

Explanation

Solution

The electronic configuration of atoms of group 15 are half filled, ie, (npx1,npy1,npz1)(np_{x}^{1},\,\,np_{y}^{1},\,\,np_{z}^{1}) and are stable therefore, they have high ionization enthalpy. Ongoing down the group, the ionization enthalpy decreases due to increase in atomic size. Hence, NN has highest ionization enthalpy.