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Question: Which of the following has been arranged in order of decreasing stability ?...

Which of the following has been arranged in order of decreasing stability ?

A

CH3+>CH3CH2+>(CH3)2CH+>(CH3)3C+CH_{3}^{+} > CH_{3}CH_{2}^{+} > (CH_{3})_{2}CH^{+} > (CH_{3})_{3}C^{+}

B

CH3CH2+>(CH3)2CH+>(CH3)3C+>CH3+CH_{3}CH_{2}^{+} > (CH_{3})_{2}CH^{+} > (CH_{3})_{3}C^{+} > CH_{3}^{+}

C

(CH3)2CH+>CH3CH2+>(CH3)3C+>CH3+(CH_{3})_{2}CH^{+} > CH_{3}CH_{2}^{+} > (CH_{3})_{3}C^{+} > CH_{3}^{+}

D

(CH3)3C+>(CH3)2CH+>CH3CH2+>CH3+(CH_{3})_{3}C^{+} > (CH_{3})_{2}CH_{}^{+} > CH_{3}CH_{2}^{+} > CH_{3}^{+}

Answer

(CH3)3C+>(CH3)2CH+>CH3CH2+>CH3+(CH_{3})_{3}C^{+} > (CH_{3})_{2}CH_{}^{+} > CH_{3}CH_{2}^{+} > CH_{3}^{+}

Explanation

Solution

(CH3)3–CÅ > (CH3)2 CH+\overset{+}{CH} > CH3CH+2{\overset{+}{CH}}_{2}>CH+3{\overset{+}{CH}}_{3}

+ I ¯ of CH3

Stability ¯