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Question

Chemistry Question on Hydrocarbons

Which of the following gives propyne on hydrolysis?

A

Al4C3Al_4C_3

B

Mg2C3Mg_2C_3

C

B4CB_4C

D

La4C3La_4C_3

Answer

Mg2C3Mg_2C_3

Explanation

Solution

Magnesium carbide on hydrolysis gives propyne. Mg2C3+4H2OCH3CCHpropyne+2Mg(OH)2Mg _{2} C _{3}+4 H _{2} O \longrightarrow \underset{\text{propyne}}{CH _{3} C \equiv CH} +2 Mg ( OH )_{2} Al4C3+12H2O3CH4Methane+4Al(OH)3Al _{4} C _{3}+12 H _{2} O \longrightarrow \underset{\text{Methane}}{3 CH _{4}} \uparrow+4 Al ( OH )_{3}