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Question

Chemistry Question on Haloalkanes and Haloarenes

Which of the following gives a white precipitate with alcoholic silver nitrate?

A

Benzyl chloride

B

Ethyl iodide

C

Vinyl chloride

D

Chlorobenzene

Answer

Benzyl chloride

Explanation

Solution

Aryl and vinyl halide's are not hydrolysed by alcoholic silver nitrate solution. Benzyl chloride gives a 'white ppt. while ethyl iodide gives yellow ppt with alcoholic silver nitrate solution.