Question
Chemistry Question on Aldehydes, Ketones and Carboxylic Acids
Which of the following does not undergo Cannizzaro reaction?
A
Benzaldehyde
B
2-Methylpropanal
C
p-Methoxybenzaldehyde
D
2,2-Dimethylpropanal
Answer
2-Methylpropanal
Explanation
Solution
Aldehydes containing no α−H atoms on heating with concentrated alkali solution (50%) undergo Cannizzaros reaction. In this reaction one molecule is oxidised at the expense of other which is reduced to alcohol.