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Question

Chemistry Question on Aldehydes, Ketones and Carboxylic Acids

Which of the following does not undergo Cannizzaro reaction?

A

Benzaldehyde

B

22-Methylpropanal

C

pp-Methoxybenzaldehyde

D

2,22,2-Dimethylpropanal

Answer

22-Methylpropanal

Explanation

Solution

Aldehydes containing no αH\alpha-H atoms on heating with concentrated alkali solution (50%)(50\%) undergo Cannizzaros reaction. In this reaction one molecule is oxidised at the expense of other which is reduced to alcohol.