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Question

Question: Which of the following does not reduce Tollen’s reagent...

Which of the following does not reduce Tollen’s reagent

A

CH3CHOCH_{3}CHO

B

C6H5NHOHC_{6}H_{5}NHOH

C

HCOOHHCOOH

D

C6H5NO2C_{6}H_{5}NO_{2}

(5) None of these

Answer

C6H5NO2C_{6}H_{5}NO_{2}

55 None of these

Explanation

Solution

CH3CONH2Acetamide+Br2+4KOH2H2O\underset{\text{Acetamide}}{CH_{3}CONH_{2}} + Br_{2} + 4KOH\overset{\rightarrow}{\quad - 2H_{2}O\quad}

CH3NH2(Methyl amine)+2KBr+2K2CO3\underset{\mathbf{(}\text{Methyl amine}\mathbf{)}}{\mathbf{C}\mathbf{H}_{\mathbf{3}}\mathbf{N}\mathbf{H}_{\mathbf{2}}}\mathbf{+ 2KBr + 2}\mathbf{K}_{\mathbf{2}}\mathbf{C}\mathbf{O}_{\mathbf{3}}