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Question

Question: Which of the following compounds will undergo Cannizzaro reaction?...

Which of the following compounds will undergo Cannizzaro reaction?

A

CH3CHO\mathrm { CH } _ { 3 } \mathrm { CHO }

B

CH3COCH3\mathrm { CH } _ { 3 } \mathrm { COCH } _ { 3 }

C

C6H5CHO\mathrm { C } _ { 6 } \mathrm { H } _ { 5 } \mathrm { CHO }

D

C6H5CH2CHO\mathrm { C } _ { 6 } \mathrm { H } _ { 5 } \mathrm { CH } _ { 2 } \mathrm { CHO }

Answer

C6H5CHO\mathrm { C } _ { 6 } \mathrm { H } _ { 5 } \mathrm { CHO }

Explanation

Solution

: Aldehydes with no αH\alpha - H atom undergo Cannizzaro reaction on heating with conc. Alkali solution. Hence, only C6H5CHO\mathrm { C } _ { 6 } \mathrm { H } _ { 5 } \mathrm { CHO }will undergo the reaction.