Question
Question: Which of the following compounds will give a yellow precipitate with iodine and alkali? \( A) \) ...
Which of the following compounds will give a yellow precipitate with iodine and alkali?
A) Methyl acetate
B) Acetamide
C) 2− Hydroxypropane
D) Acetophenone
Solution
Ethanol is the solitary essential alcohol to give the triiodomethane response. Assuming " R " is a hydrocarbon group, you have an optional Alcohol. Loads of optional alcohols give this response, yet those that do all have a methyl group appended to the carbon with the - OH group.To find the yellow precipitate, we must know the type of reaction which is taking place. The iodoform reaction is taking place.
Complete answer:
The formation of iodoform is responsible for formation of yellow precipitate. Iodoform (CH3I) is yellow in color and has a penetrating odour.
Iodoform is defined as a substance reaction in which a methyl ketone is oxidized to a carboxylate by reaction with aqueous HO and I2 . The reaction additionally delivers iodoform, a yellow strong which may hasten from the reaction blend. The iodoform response has been utilized as a substance test for the presence of a methyl ketone moiety.
C6H5COCH3+NaOH+I2→C6H5CO2Na+CHI3
Methyl acetate and acetamide will not undergo an iodoform test.
Correct options are C) and D) .
Note:
Iodoform, likewise called triiodomethane, a yellow, crystalline solid having a place with the group of natural halogen compounds, utilized as a clean part of prescriptions for minor skin infections. The haloform reaction is the reaction of a methyl ketone with chlorine, bromine, or iodine within the sight of hydroxide particles to give a carboxylate particle and a haloform. There is one aldehyde that goes through the haloform reaction, which is acetaldehyde.