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Question

Chemistry Question on coordination compounds

Which of the following compounds shows optical isomerism?

A

CH3CHBrCOOHCH_{3}-CH-BrCOOH

B

CH2OHCH2COOHCH_{2}OHCH_{2}-COOH

C

COOHCHBrCOOHCOOHCHBr-COOH

D

CH2BrCH2COOH CH_{2}Br-CH_{2}-COOH

Answer

CH3CHBrCOOHCH_{3}-CH-BrCOOH

Explanation

Solution

Optical isomerism is exhibited by asymmetric compounds. Compounds having chiral carbon atom are usually asymmetric and exhibit optical isomerism. CH3CH(Br)COOH CH_{3}\overset{*}{C}H(Br)COOH , due to the presence of chiral carbon atom, exhibits optical isomerism. [C= \overset{*}{C}= chiral carbon, the carbon four valencies of which are attached with four different groups.]