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Question

Question: Which of the following compounds is/are metamers? (This question has multiple correct options). A....

Which of the following compounds is/are metamers? (This question has multiple correct options).
A.) Diethyl ether
B.) 22 - Methoxy propane
C.) 11 - Methoxy propane
D.) Butanal

Explanation

Solution

Metamers are those compounds which have the same molecular formula but they have different alkyl groups on either side of functional groups. So, in given compounds we will find out which of the following have the same molecular formulas but different alkyl groups.

Complete step by step answer:
In this question, metamer is a compound that exhibits metamerism with one or more compounds. These compounds have the same molecular formula but different number of carbon atoms on either side of the functional group. Metamerism occurs among the members of the same homologous family.
In option A.)
The diethyl ether has the general formula C4H10O{C_4}{H_{10}}O. The structure of diethyl ether can be shown as:

In option B.)
The 22 - Methoxy propane has the general chemical formula as C4H10O{C_4}{H_{10}}O. The structure of 22 - Methoxy propane can be represented as:

In option C.)
The 11 - Methoxy propane has the general chemical formula as C4H10O{C_4}{H_{10}}O. The structure of 11 - Methoxy propane can be represented as:

In option D.)
The Butanal has the general chemical formula as C4H8O{C_4}{H_8}O. The structure of butanal can be represented as:

As we can see that Diethyl ether, 22 - Methoxy propane and 11 - Methoxy propane , all of them have same molecular formula that is C4H10O{C_4}{H_{10}}O.Also, all of them have different alkyl groups on either side of the functional group. Therefore, Diethyl ether, 22 - Methoxy propane and 11 - Methoxy propane are metamers of each other.

Hence, A, B and C are correct options.

Note:
Remember that metamerism is one of the types of structural isomerism because the compounds that show structural isomers have the same molecular formula but different in arrangement of atoms within the molecule. In metamerism, arrangement is different about a functional group.