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Question

Chemistry Question on Hydrocarbons

Which of the following compounds has least boiling point?

A

2-Methylbutane

B

n-Hexane

C

n-Pentane

D

2,2-Dimethylpropane

Answer

2,2-Dimethylpropane

Explanation

Solution

Boiling point of alkanes increases with increase in molecular mass and among isomers of the same compound it decreases with increase in branching. Hence the order of boiling point is n-Hexane > n-Pentane > 2-Methylbutane > 2,2-Dimethylpropane