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Question

Chemistry Question on Hydrocarbons

Which of the following compounds does not dissolve in cone. H2SO4H_2S O_4 even on warming?

A

Ethylene

B

Benzene

C

Hexane

D

Aniline

Answer

Hexane

Explanation

Solution

The correct answer is C:Hexane
Ethylene absorb H2SO4H_2S O_4 forming CH3CH2OSO3HCH_3-CH_2 OSO_3 H and dissolve. Benzene, with warm H2SO4,H_2S O_4, undergo sulphonation
and dissolve. Aniline, with H2SO4,H_2S O_4, forms anilinium sulphate salt and dissolve. Hexane, a hydrophobic molecule, does not react with H2SO4,H_2S O_4,
remains insoluble.