Question
Chemistry Question on Aldehydes, Ketones and Carboxylic Acids
Which of the following compound would undergo Aldol condensation?
Methanal
Benzaldehyde
2,2−Dimethylbutanal
Phenylacetaldehyde
Benzaldehyde
Solution
The compound that would undergo Aldol condensation is **Benzaldehyde. **
Aldol condensation is a reaction between an aldehyde or ketone with an enolate ion formed from the same or a different molecule. Benzaldehyde has an aldehyde functional group and can readily undergo Aldol condensation. In this reaction, the alpha carbon of the aldehyde is deprotonated by a base to form an enolate ion, which then reacts with another molecule of the aldehyde to form a beta-hydroxy aldehyde (aldol).
The aldol product can undergo subsequent dehydration to form an α,β-unsaturated aldehyde.
Therefore, the correct option is (B): among the given compounds, Benzaldehyde is the one that would undergo Aldol condensation.