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Question

Chemistry Question on Aldehydes, Ketones and Carboxylic Acids

Which of the following compound would undergo Aldol condensation?

A

MethanalMethanal

B

BenzaldehydeBenzaldehyde

C

2,2Dimethylbutanal2,2-Dimethylbutanal

D

PhenylacetaldehydePhenylacetaldehyde

Answer

BenzaldehydeBenzaldehyde

Explanation

Solution

The compound that would undergo Aldol condensation is **Benzaldehyde. **

Aldol condensation is a reaction between an aldehyde or ketone with an enolate ion formed from the same or a different molecule. Benzaldehyde has an aldehyde functional group and can readily undergo Aldol condensation. In this reaction, the alpha carbon of the aldehyde is deprotonated by a base to form an enolate ion, which then reacts with another molecule of the aldehyde to form a beta-hydroxy aldehyde (aldol).

The aldol product can undergo subsequent dehydration to form an α,β-unsaturated aldehyde.

Therefore, the correct option is (B): among the given compounds, Benzaldehyde is the one that would undergo Aldol condensation.