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Question

Chemistry Question on Aldehydes, Ketones and Carboxylic Acids

Which of the following compound gives iodoform test?

A

CH3CNCH_{3}CN

B

CH3OHCH_{3}OH

C

CH3COCH3CH_{3}COCH_{3}

D

C6H5OHC_{6}H_{5}OH

Answer

CH3COCH3CH_{3}COCH_{3}

Explanation

Solution

Compounds containing
(CH3CO)\left(CH_{3} -\overset{\underset{||}{O}}{C}- \right)
group give the iodoform test.
CH3COCH3+3I2+NaOHCHI3+HCOONa+H2O Iodoform (yellow ppt) CH _{3}- \overset{\underset{||}{O}}{C} - CH _{3}+3 I _{2}+ Na OH \longrightarrow\underset{\text { Iodoform (yellow ppt) }}{ CHI _{3}+ HCOONa + H _{2} O }
Hence only acetone gives the iodoform test.