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Question

Question: Which of the following complexes formed by \(Cu^{2 +}\)ions is most stable?...

Which of the following complexes formed by Cu2+Cu^{2 +}ions is most stable?

A

Cu2++4NH3Cu^{2 +} + 4NH_{3} [Cu(NH3)4]2+,\lbrack Cu(NH_{3})_{4}\rbrack 2 + ,log K = 11.611.6

B

Cu2++4CNCu^{2 +} + 4CN^{-} [Cu(CN)4]2,\lbrack Cu(CN)_{4}\rbrack^{2 -}, log K = 27.327.3

C

Cu2++2enCu^{2 +} + 2en [Cu(en)2]2+,\lbrack Cu(en)_{2}\rbrack^{2 +}, log K = 15.415.4

D

Cu2++4H2OCu^{2 +} + 4H_{2}O [Cu(H2O)4]2+\lbrack Cu(H_{2}O)_{4}\rbrack^{2 +}, log K = 8.98.9

Answer

Cu^{2 +} + 4CN^{-}$$\lbrack Cu(CN)_{4}\rbrack^{2 -}, log K = 27.327.3

Explanation

Solution

Higher the value of stability constant K, greater is the stability.