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Question

Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques

Which of the following carbocation is most stable?

A

(CH3)3C.C+H2(CH_3)_3C.C^+H_2

B

(CH3)3C+(CH_3)_3C^+

C

CH3CH2C+H2CH_3CH_2C^+H_2

D

CH3C+HCH2CHCH_3C^+H CH_2CH

Answer

(CH3)3C+(CH_3)_3C^+

Explanation

Solution

(CH3)3C+(CH_3)_3C^+ is a tertiary carbocation. A tertiary carbocation is the most stable carbocation due to the electron-releasing effect of three methyl groups. An increased + I effect by three methyl groups stabilizes the positive charge on the carbocation.