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Question

Chemistry Question on d -and f -Block Elements

Which of the following can give iodometric titration?

A

Fe+3Fe ^{+3}

B

Cu+2Cu ^{+2}

C

Pb+2Pb ^{+2}

D

Ag+2Ag ^{+2}

Answer

Cu+2Cu ^{+2}

Explanation

Solution

2Cu2++2ICu2I2+I22 Cu ^{2+}+2 I ^{-} \rightarrow Cu _{2} I _{2}+ I _{2} \uparrow 2S2O32+I2thioslphate)S4O62+2I \underset{\text{thioslphate)}}{{2 S _{2} O _{3}{ }^{2-}+ I _{2} }}\rightarrow S _{4} O _{6}{ }^{2-}+2 I ^{-} Iodometric titration involves the evolution of iodine immediately before adding thiosulphate solution.