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Question

Chemistry Question on Methods of Preparation of Haloalkanes

Which of the following can give a Grignard reagent when reacted with magnesium m dry ether?

A

C2H6{{C}_{2}}{{H}_{6}}

B

C2H5Cl{{C}_{2}}{{H}_{5}}Cl

C

C2H5OH{{C}_{2}}{{H}_{5}}OH

D

C2H5CN{{C}_{2}}{{H}_{5}}CN

Answer

C2H5Cl{{C}_{2}}{{H}_{5}}Cl

Explanation

Solution

C2H5Cl{{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}\text{Cl} can give Grignard reagent when reacted with Mg in dry ether. RX+Mg(dry)DryetherRMgXRX+Mg(dry)\xrightarrow{\text{Dry}\,\text{ether}}RMgX C2H5Cl+MgDryetherC2H5MgClEthylmagneslumchloride{{C}_{2}}{{H}_{5}}Cl+Mg\underset{\,\,\,\,\,\,\,\,\,\,\,\,\,\text{Ethyl}\,\text{magneslum}\,\text{chloride}}{\mathop{\xrightarrow{\text{Dry}\,\text{ether}}{{C}_{2}}{{H}_{5}}MgCl}}\,