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Question: Which of the following are arranged in the decreasing order of dipole moment?...

Which of the following are arranged in the decreasing order of dipole moment?

A

CH3Cl,CH3Br,CH3FCH_{3}Cl,CH_{3}Br,CH_{3}F

B

CH3Cl,CH3F,CH3BrCH_{3}Cl,CH_{3}F,CH_{3}Br

C

CH3Br,CH3Cl,CH3FCH_{3}Br,CH_{3}Cl,CH_{3}F

D

CH3Br,CH3F,CH3ClCH_{3}Br,CH_{3}F,CH_{3}Cl

Answer

CH3Cl,CH3F,CH3BrCH_{3}Cl,CH_{3}F,CH_{3}Br

Explanation

Solution

: The values of dipole moments of methyl halides:

CH3F1.51D;CH_{3}F - 1.51D; CH3Cl1.56D;CH_{3}Cl - 1.56D;

CH3Br1.4D;CH_{3}Br - 1.4D; CH3I1.29DCH_{3}I - 1.29D

CH3Cl>CH3F>CH3Br>CH3l\therefore CH_{3}Cl > CH_{3}F > CH_{3}Br > CH_{3}l