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Question

Question: Which of the following alkyl halides undergoes hydrolysis water aqueous KOH at the faster rate?...

Which of the following alkyl halides undergoes hydrolysis water aqueous KOH at the faster rate?

A

CH3CH2CH2ClCH_{3}CH_{2}CH_{2}Cl

B

CH3CH2ClCH_{3}CH_{2}Cl

C

CH3CH2CH2CH2ClCH_{3}CH_{2}CH_{2}CH_{2}Cl

D

CH3CH2CH(Br)CH3CH_{3}CH_{2}CH(Br)CH_{3}

Answer

CH3CH2CH(Br)CH3CH_{3}CH_{2}CH(Br)CH_{3}

Explanation

Solution

CH3CH2CBrHCH3CH_{3}CH_{2}\underset{\underset{Br}{|}}{C}HCH_{3}will undergo hydrolysis at the faster rate because rate of reaction for hydrolysis of alkyl halides is in the order 3>2>13{^\circ} > 2{^\circ} > 1{^\circ}