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Question

Question: Which of the following alcohols reacts most readily with Lucas reagent?...

Which of the following alcohols reacts most readily with Lucas reagent?

A

CH3CH2CH2OHCH_{3}CH_{2}CH_{2}OH

B

C

CH3CH3COHCH3\begin{matrix} CH_{3} \\ | \\ CH_{3} - C - OH \\ | \\ CH_{3} \end{matrix}

D

Answer

CH3CH3COHCH3\begin{matrix} CH_{3} \\ | \\ CH_{3} - C - OH \\ | \\ CH_{3} \end{matrix}

Explanation

Solution

The rate of reaction with Lucas reagent is 3º>2º>1º3º > 2º > 1º

Tertiary alcohos immediately react to give turbidity secondary alcohols after some time and primary alcohols do not give turbidity until heated.