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Question

Chemistry Question on Chemical bonding and molecular structure

Which of the dd -orbital is used in sp3dsp^3d hybridisation?

A

dxyd_{xy}

B

dx2y2d_{x^2-y^2}

C

dz2d_{z^2}

D

dyzd_{yz}

Answer

dz2d_{z^2}

Explanation

Solution

The hybridisation of one ss, one dd and three pp-orbitals on a central atom gives rise to five sp3dsp^3d orbitals, three equatorial and two axial. This hybridisation uses one dz2d_z^2, one ss and all three of the pp orbitals and shape of the molecule becomes trigonal bipyramidal.