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Question

Question: Which of the aldehyde is most reactive?...

Which of the aldehyde is most reactive?

A

C6H5CHO\mathrm { C } _ { 6 } \mathrm { H } _ { 5 } - \mathrm { CHO }

B

CH3CHO\mathrm { CH } _ { 3 } \mathrm { CHO }

C

D

All the equally reactive

Answer

Explanation

Solution

Among Carbonyl Compounds, reactivity decrease with increase in alkyl groups as alkyl groups (+I effect) decrease positive character on C-atom. Thus, the correct order of reactivity is

HCHO>CH3CHO>C6H5CHO\mathrm { HCHO } > \mathrm { CH } _ { 3 } \mathrm { CHO } > \mathrm { C } _ { 6 } \mathrm { H } _ { 5 } \mathrm { CHO }