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Question: Which of following is more acidic in its following aqueous A. \[{H_2}O\] B. \({H_2}S\) C.\({H...

Which of following is more acidic in its following aqueous
A. H2O{H_2}O
B. H2S{H_2}S
C.H2Se{H_2}Se
D.H2Te{H_2}Te.

Explanation

Solution

Acid strength measures the ability of the acid to lose its H+ ion. Higher the H+{H^ + } ion loss in aqueous solution higher will be acidic strength. A strong acid completely ionizes in a solution whereas a weak acid only partially ionizes.

Complete answer:
The strength of an acid depends on the following two factors.
Strength of HAH - A bond
Polarity of HAH - A bond
In general if the strength of HAH - A bond is weaker, the acid will be stronger . Similarly, if the polarity of HAH - A bond is greater, stronger is the acid. These two factors make the dissociation of acid molecules into H+{H^ + } and AA- easier results in the increase in the acidity.
As the atom becomes larger, the bond gets weaker. Consequently, acid strength increases therefore the atomic size of AA also affects the acid strength.
So in option no (A) H2O{H_2}O will be least acidic because H-A bond is stronger in H2O also atomic size of Oxygen atom is least in its group therefore bond will be stronger and it will be least acid.
Similarly TeTe is the largest atom in the above option. So TeTe will have the weakest H-A bond and strongest acidic character. Also the polarity of TeTeis greatest among options.
So the correct option is option D.

Note: However, bond strength is a more determining factor when we consider and compare acid strengths of elements in the same group of the periodic table, using the above two factors.