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Question

Chemistry Question on Bond Parameters

Which is the correct decreasing order of bond angle in the following series?

A

NH3>H2O>H2SN{{H}_{3}}>{{H}_{2}}O>{{H}_{2}}S

B

H2S>NH3>H2O{{H}_{2}}S>N{{H}_{3}}>{{H}_{2}}O

C

H2S>H2O>NH3{{H}_{2}}S>{{H}_{2}}O>N{{H}_{3}}

D

H2O>NH3>H2S{{H}_{2}}O>N{{H}_{3}}>{{H}_{2}}S

Answer

NH3>H2O>H2SN{{H}_{3}}>{{H}_{2}}O>{{H}_{2}}S

Explanation

Solution

: For NH3N{{H}_{3}} bond angle (HNH)(H\overset{\wedge }{\mathop{N}}\,H) is 107107{}^\circ . For H2O{{H}_{2}}O bond angle (HOH)(H\overset{\wedge }{\mathop{O}}\,H) is 104.5104.5{}^\circ . For H2S{{H}_{2}}S bond angle (HSH)(H\overset{\wedge }{\mathop{S}}\,H) is 9292{}^\circ .