Question
Question: Which is more basic \[A{l_2}{O_3}\]or\[MgO\]?...
Which is more basic Al2O3orMgO?
Solution
Keep in mind the periodic table while answering this question. Mg belongs to the s block whereas Al belongs to the p block. Thus we can say that Mg is left to Al in terms of a period.
Also consider that Al2O3 is an amphoteric oxide. Metal oxides which react with both acids as well as bases to produce salts and water are known as amphoteric oxides. As a rule all the metal oxides will be basic and all the non-metal oxides are acidic.
Complete answer:
There are many things that point out to the fact that MgO is more basic than Al2O3.
We observe that metals are mostly present on the left side of the periodic table and nonmetals towards the right side of a period. Since the oxides of non-metals are acidic and that of metals are basic we say that along a period from left to right basic character decreases.
Observing the periodic table and the positions of Mg and Al we can conclude that MgOis more basic than Al2O3.
Another point that confirms the answer is that Al2O3 is an amphoteric oxide whereas MgO is a basic metal oxide. Which gives us more confirmation that MgO is more basic thanAl2O3
Note:
K2O | MgO | Al2O3 | SiO2 | CO2 |
---|---|---|---|---|
Strongly Basic | Basic | Amphoteric | Weakly Acidic | Acidic |
Also as we go down a group the basicity of oxides increases with increases. For example in group V, NO2and P4O8 are acidic, As2O4and Sb2O3 are amphoteric, Bi2O3 is basic.
Even when we consider the oxides of the second group elements basicity increase in the following order
BeO < MgO < CaO < SrO < BaO