Solveeit Logo

Question

Question: Which is more basic \[A{l_2}{O_3}\]or\[MgO\]?...

Which is more basic Al2O3A{l_2}{O_3}orMgOMgO?

Explanation

Solution

Keep in mind the periodic table while answering this question. Mg belongs to the s block whereas Al belongs to the p block. Thus we can say that Mg is left to Al in terms of a period.
Also consider that Al2O3A{l_2}{O_3} is an amphoteric oxide. Metal oxides which react with both acids as well as bases to produce salts and water are known as amphoteric oxides. As a rule all the metal oxides will be basic and all the non-metal oxides are acidic.

Complete answer:
There are many things that point out to the fact that MgOMgO is more basic than Al2O3A{l_2}{O_3}.
We observe that metals are mostly present on the left side of the periodic table and nonmetals towards the right side of a period. Since the oxides of non-metals are acidic and that of metals are basic we say that along a period from left to right basic character decreases.
Observing the periodic table and the positions of Mg and Al we can conclude that MgOMgOis more basic than Al2O3A{l_2}{O_3}.
Another point that confirms the answer is that Al2O3A{l_2}{O_3} is an amphoteric oxide whereas MgOMgO is a basic metal oxide. Which gives us more confirmation that MgOMgO is more basic thanAl2O3A{l_2}{O_3}

Note:

K2O{K_2}OMgOMgOAl2O3A{l_2}{O_3}SiO2Si{O_2}CO2C{O_2}
Strongly BasicBasicAmphotericWeakly AcidicAcidic

Also as we go down a group the basicity of oxides increases with increases. For example in group V, NO2N{O_2}and P4O8{P_4}{O_8} are acidic, As2O4A{s_2}{O_4}and Sb2O3S{b_2}{O_3} are amphoteric, Bi2O3B{i_2}{O_3} is basic.
Even when we consider the oxides of the second group elements basicity increase in the following order
BeO < MgO < CaO < SrO < BaOBeO{\text{ }} < {\text{ }}MgO{\text{ }} < {\text{ }}CaO{\text{ }} < {\text{ }}SrO{\text{ }} < {\text{ }}BaO