Question
Question: Which has a higher \(pH\) value-\(0.01M\) \(NaOH\) or \(0.1M\) \(NaHC{O_3}\)?...
Which has a higher pH value-0.01M NaOH or 0.1M NaHCO3?
Solution
pH is a scale used to specify the acidity or basicity of an aqueous solution. Acidic solutions are measured to have lower pH values than basic or alkaline solutions. The pH scale is logarithmic and inversely indicates the concentration of hydrogen ions in the solution. This is because the formula used to calculate pH approximates the negative of the base 10 logarithm of the molar concentration of hydrogen ions in the solution.
Complete answer:
pH is a measure of how acidic or basic water is. The range goes from 0 to 14, with 7 being neutral. pH of less than 7 indicates acidity, whereas a pH of greater than 7 indicates a base. pH is really a measure of the relative amount of free hydrogen and hydroxyl ions in the water.
To calculate the pH of 0.01M NaOH
First we calculate the pOH, because when we dissolve the NaOH in water NaOH dissociates into Na+ and OH−.
⇒pOH=−log[OH−]
⇒pOH=−log[0.01]=2
We know that the
⇒pH+pOH=14
⇒pH=14−2=12
So, the pH of 0.01M NaOH is 12
And the pH of 0.1M NaHCO3 is 8.3
So, the pH of 0.01M NaOH is higher than 0.1M NaHCO3.
Note:
Indicators may be used to measure pH, by making use of the fact that their color changes with pH.Visual comparison of the color of a test solution with a standard color chart provides a means to measure pH accurate to the nearest whole number. More precise measurements are possible if the color is measured spectrophotometrically, using a colorimeter or spectrophotometer. Universal indicator paper is made from absorbent paper that has been impregnated with universal indicator. Another method of measuring pHis using an electronic pH meter.