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Question

Chemistry Question on Chemical Reactions

Which does not react with Fehling solution?

A

CH3CHOCH_{3}CHO

B

C6H5CHOC_{6}H_{5}CHO

C

CH3COCH3CH_{3}COCH_{3}

D

glucose

Answer

CH3COCH3CH_{3}COCH_{3}

Explanation

Solution

Aldehydes are oxidised by Fehling solution, while ketones do not react with Fehling solution RCHO+2Cu2+[from Fehling solution]+3OHRCOO+2CuRed+2H2ORCHO+\underset{\text{[from Fehling solution]}}{2Cu^{2+}}+3OH^{-} \to RCOO^{-}+\underset{\text{Red}}{{2Cu}} \downarrow +2H_{2}O