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Question

Pharmaceutical Analysis Question on Oxidation-reduction titrations

Which among the following statements related to Ceric sulphate as oxidizing agent, as titrant are correct

A

Ce (IV) during reaction exists as an anionic complex in media of sulphuric acid

B

Ionic equation is Ce3+Ce2++eCe^{3+}→Ce^{2+} + e^{-}

C

Formal potential of Ce(III) Ce (II) couple is 1

D

Ce (IV) does not permit use of HCl as reducing media

Answer

Ce (IV) during reaction exists as an anionic complex in media of sulphuric acid

Explanation

Solution

The correct option is (A) : Ce (IV) during reaction exists as an anionic complex in media of sulphuric acid