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Question

Chemistry Question on Spontaneity

When the same quantity of heat is absorbed by a system at two different temperatures T1T_1 and T2T_2, such that T1>T2T_1 > T_2, change in entropies are ΔS1\Delta S_1 and ΔS2\Delta S_2 respectively. Then

A

ΔS1<ΔS2\Delta S_1 < \Delta S_2

B

ΔS1=ΔS2\Delta S_1 = \Delta S_2

C

S1>S2S_1 > S_2

D

ΔS2<ΔS1\Delta S_2 < \Delta S_1

Answer

ΔS1<ΔS2\Delta S_1 < \Delta S_2

Explanation

Solution

In thermodynamics, we are concerned about entropy change due to the transfer of heat.

Which we can write in the form, ΔS=q/T\Delta S = q / T, here qq is constant.

So, ΔS1/T\Delta S \propto 1 / T

We are given, T1>T2T _{1}> T _{2}, so the actual relation between the entropies will be $\Delta S _{1}