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Question: When the mixture of \(MgC{{O}_{3}}\)and \(CaC{{O}_{3}}\)was heated for a long time, the weight decre...

When the mixture of MgCO3MgC{{O}_{3}}and CaCO3CaC{{O}_{3}}was heated for a long time, the weight decreased by 50%. Calculate the percentage composition of the mixture.

Explanation

Solution

Percent composition of any compound can be defined as the ratio of the amount of every individual element to the total amount of individual elements present in the compound multiplied by 100. This helps in chemical analysis of given compounds.

Complete answer:
Hence to find out the percentage composition first consider the total mass will be 100 g then suppose
Weight of MgCO3MgC{{O}_{3}}= x gm
This implies Weight of CaCO3CaC{{O}_{3}}= 100-x gm as total weight is 100 g
Now the reaction of magnesium and calcium carbonate upon heating can be shown as:
MgCO3MgO+CO2MgC{{O}_{3}}\to MgO+C{{O}_{2}}
CaCO3CaO+CO2CaC{{O}_{3}}\to CaO+C{{O}_{2}}
Number of moles of magnesium carbonate will be given as x84\dfrac{x}{84}
Number of moles of calcium carbonate is given as 100x100\dfrac{100-x}{100}
Now the weight of CO2C{{O}_{2}}evolved in MgCO3MgC{{O}_{3}} will be calculated by multiplying the number of moles into its molar mass which will be given as follows:
x84×44g\dfrac{x}{84}\times 44g
Similarly the weight of CO2C{{O}_{2}}evolved in CaCO3CaC{{O}_{3}} will be given as follows:
100x100×44g\dfrac{100-x}{100}\times 44g
According to question weight loss given is 50%, therefore
x84×44+100x100×44g=50\dfrac{x}{84}\times 44+\dfrac{100-x}{100}\times 44g=50, here 50 is 50% of 100 g
x84+100x100=5044\dfrac{x}{84}+\dfrac{100-x}{100}=\dfrac{50}{44}
Now by solving the above equation the value of x will be 71.59%
This implies that % of MgCO3MgC{{O}_{3}}= x100×100=71.59\dfrac{x}{100}\times 100=71.59%
% of CaCO3CaC{{O}_{3}}= 100-x = 28.41%

Note:
Mole is generally represented by the symbol mol. It is generally described as the unit of measurement for the amount of substance in SI where SI stands for International System of units. It is defined on the basis of Avogadro’s number.