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Question

Chemistry Question on Redox reactions

When MnO2\text{MnO}_2 and H2SO4\text{H}_2\text{SO}_4 is added to a salt (A), the greenish yellow gas liberated as salt (A) is:

A

NaBr\text{NaBr}

B

CaI2\text{CaI}_2

C

KNO3\text{KNO}_3

D

NH4Cl\text{NH}_4\text{Cl}

Answer

NH4Cl\text{NH}_4\text{Cl}

Explanation

Solution

The reaction involved is:
2NH4Cl+MnO2+2H2SO4ΔMnSO4+(NH4)2SO4+2H2O+Cl22\text{NH}_4\text{Cl} + \text{MnO}_2 + 2\text{H}_2\text{SO}_4 \xrightarrow{\Delta} \text{MnSO}_4 + (\text{NH}_4)_2\text{SO}_4 + 2\text{H}_2\text{O} + \text{Cl}_2 \uparrow
In this reaction, chlorine gas (Cl2\text{Cl}_2) is liberated, which has a greenish-yellow color.