Question
Question: When sodium reacts with excess of oxygen, the oxidation number of oxygen changes from: \[A.\, \,0\...
When sodium reacts with excess of oxygen, the oxidation number of oxygen changes from:
A.0to−1
B.0to−2
C.−1to−2
D.nochange
Solution
When the sodium reacts with the excess amount of the oxygen It leads to the formations of metal oxide that is the sodium peroxide. When the sodium is heated and put into a jar containing the oxygen it will lead to generating a lot of light and heat energy, and it forms white powder after the reaction i.e., sodium oxide.
Complete step by step solution:
The sodium metal is more reactive than the lithium (Li), and it readily reacts with water (H2O ) to form a sodium hydroxide (NaOH) which is one the strong base and it is used in labs, industries, etc. This reaction is highly exothermic that liberates heat.
The equation is given below;
2Na+H2O→NaOH+21H2
When the sodium (Na) metal is reacted with an excess amount of air or oxygen(O2 ) , it produces sodium peroxide.
The equation is given below;
2Na+O2→Na2O21−
Let’s write the charge for each element,
2Na1++O20→Na2O21−
So, here the oxidation number of oxygen is getting changed from $$$$ .
Therefore, the correct answer is optionA.0to−1 .
Additional information:
When sodium metal reacts with oxygenO2 at the temperature of 200− 350 ∘C , it produces sodium oxide Na2O
4Na+O2→2Na2O
When sodium metal reacts with excess oxygen O2 at the temperature of 350− 450 ∘C , it produces sodium peroxide Na2O2
2Na2O+O2→2Na2O2
Note: The sodium peroxide Na2O2 is an inorganic compound which is yellowish in colour. In sodium oxideNa2O , the oxygen is having −2 , which is one of the very strong bases and has a high tendency to combine with the ions hydrogen.
When sodium peroxide Na2O2 reacts with excess oxygen O2 at the high pressure, it produces sodium superoxideNaO2
2Na2O2+O2→2NaO2