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Question

Chemistry Question on p -Block Elements

When metal ? MM ? is treated with NaOHNaOH, a white gelatinous precipitate ?XX? is obtained, which is soluble in excess of NaOHNaOH. Compound ?XX? when heated strongly gives an oxide which is used in chromatography as an adsorbent. The metal ?MM? is :

A

Zn

B

Ca

C

Al

D

Fe

Answer

Al

Explanation

Solution

Al3+>[NaOH]Al(OH)3White gelatinous ppt.>[ ExcessNaOH]NaAlO2Sodium meta aluminate (soluble)Al ^{3+} {->[{ NaOH }]} \underset{\text{White gelatinous ppt.}}{ Al ( OH )_{3} \downarrow} {->[{{\text{ Excess}}}\,{ NaOH }]} \underset{\text{Sodium meta aluminate (soluble)}}{NaAlO _{2}}
2Al(OH)3>[ Strong heating ]Al2O3+3H2O2 Al ( OH )_{3} {->[{\text { Strong heating }}]} Al _{2} O _{3}+3 H _{2} O
Al2O3Al _{2} O _{3} is used in column chromatography.