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Question

Question: When \(KMnO_{4}\) reacts with acidified \(FeSO_{4}\)....

When KMnO4KMnO_{4} reacts with acidified FeSO4FeSO_{4}.

A

Only FeSO4FeSO_{4} is oxidized

B

Only KMnO4KMnO_{4} is oxidized

C

FeSO4FeSO_{4} is oxidised KMnO4KMnO_{4} and is reduced

D

None of these

Answer

FeSO4FeSO_{4} is oxidised KMnO4KMnO_{4} and is reduced

Explanation

Solution

FeSO4FeSO_{4}is oxidised and KMnO4KMnO_{4} is reduced.

[2FeSO4+H2SO4Fe2(SO4)3+2H]×5\lbrack 2FeSO_{4} + H_{2}SO_{4} \rightarrow Fe_{2}(SO_{4})_{3} + 2H\rbrack \times 5

[2H+[O]H2O]×5\lbrack 2H + \lbrack O\rbrack \rightarrow H_{2}O\rbrack \times 5

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2KMnO4+8H2SO4+10FeSO42KMnO_{4} + 8H_{2}SO_{4} + 10FeSO_{4} \rightarrow

K2SO4+2MnSO4+5Fe2(SO4)3+8H2OK_{2}SO_{4} + 2MnSO_{4} + 5Fe_{2}(SO_{4})_{3} + 8H_{2}O

In this reaction oxidation state of MnMn is changing from +7 to +2 while oxidation state of FeFe is changing from +2 to +3.