Question
Question: When \(KMn{O_4}\) reacts with \(B{r_2}\) in a weak alkaline medium gives bromate ion. Then oxidation...
When KMnO4 reacts with Br2 in a weak alkaline medium gives bromate ion. Then oxidation state of Mn changes from +7 to:
- +6
2)+4 - +3
- +2
Solution
We know that the oxidation state, at times alluded to as oxidation number, depicts the level of oxidation (loss of electrons) of a molecule in a synthetic compound. Adroitly, the oxidation state, which might be positive, negative or zero, is the theoretical charge that an iota would have if all bonds to particles of various components were 100% ionic, with no covalent segment. This is never precisely valid for genuine bonds.
Complete answer:
2MnO4−+Br−+H2O2MnO2+BrO3−+2OH−
Let us calculate the oxidation of manganese in MnO2,
x+2(−2)=0
⇒x=+4
Thus the oxidation state changes from +7 to +4.
Hence option 2 is correct.
Additional information:
Potassium permanganate is an inorganic compound with the synthetic equation KMnO4 and made out of K+ and MnO4−. It is a purplish-dark glasslike salt that disintegrates in water to give seriously pink or purple arrangements. Potassium permanganate is broadly utilized in the compound industry and labs as a solid oxidizing specialist, and furthermore as a drug for dermatitis, for cleaning wounds, and general sterilization.
Note:
As we know that potassium permanganate can be utilized to quantitatively decide the absolute oxidizable natural material in a fluid example. The worth decided is known as the permanganate esteem. In logical science, a normalized fluid arrangement of KMnO4 is now and again utilized as an oxidizing titrant for redox titrations (permanganometry). As potassium permanganate is titrated, the arrangement turns into a light shade of red, which obscures as overabundance of the titrant is added to the arrangement. In a connected manner, it is utilized as a reagent to decide the Kappa number of wood mash. For the normalization of KMnO4 arrangements, decrease by oxalic corrosive is frequently used. Watery, acidic arrangements of KMnO4 are utilized to gather vaporous mercury in pipe gas during fixed source emanations testing.