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Question

Chemistry Question on Stoichiometry and Stoichiometric Calculations

When Fe0.93OFe _{0.93} O is heated in presence of oxygen, it converts to Fe2O3Fe _2 O _3 The number of correct statement/s from the following is
A. The equivalent weight of Fe093OFe _{093} O is Molecular wejght 0.790.79
B. The number of moles of Fe2+Fe ^{2+} and Fe3+Fe ^{3+} in 1 mole of Fe0.93OFe _{0.93} O is 0.790.79 and 014014 respectively
C. Fe0.93OFe _{0.93} O is metal deficient with lattice comprising of cubic closed packed arrangement of O2O ^{2-} ions
D. The %\% composition of Fe2+Fe ^{2+} and Fe3+Fe ^{3+} in Fe093OFe _{093} O is 85%85 \% and 15%15 \% respectively

Answer

The correct answer is 4.
A : Fe0.93​O→Fe2​O3​
nf=(3−93200​)×0.93
nf=0.79
B: 2x+(0.93−x)×3=2
x=0.79
Fe2+=0.79,Fe3+=0.21
C : Fact
D : %Fe2+=0.930.79​×100=85%;Fe3+=15%