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Question

Chemistry Question on Enthalpy change

When equal volume of 1M HCl and 1M H2_2SO4_4 are separately neutralized by excess volume of 1M NaOH solution, X and Y kJ of heat is liberated respectively. The value of Y/X is ____.

Answer

Neutralization reactions:

H++OHH2O(from HCl: X),\mathrm{H^+ + OH^- \rightarrow H_2O} \quad (\text{from HCl: } X),
2H++2OH2H2O(from H2SO4:Y).\mathrm{2H^+ + 2OH^- \rightarrow 2H_2O} \quad (\text{from } H_2SO_4: Y).

From the reactions:

Y=2X    YX=2.Y = 2X \implies \frac{Y}{X} = 2.

Final Answer: 2.