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Question

Chemistry Question on p -Block Elements

When CO2CO_2 is passed through solution of sodium aluminate, precipitate of which compound is formed?

A

Al(OH)3Al(OH)_3

B

Al2O3Al_2O_3

C

Na2CO3Na_2CO_3

D

No ppt

Answer

Al(OH)3Al(OH)_3

Explanation

Solution

In Hall?? process, for purifying the bauxite ore, the solution containing sodium meta aluminate is warmed to 50-60^{\circ}C and carbon dioxide is circulated through it, Al(OH) separates out as precipitate. 2NaAlO2+CO2+3H2O>2Al(OH)3+Na2CO3 {2NaAlO2 + CO2 + 3H2O -> 2Al(OH)3 + Na2CO3}